Thermal interface materials (TIM) are a critical part of the cooling system when using top sided cooling. Since GaN devices are very small, effective cooling relies on the heat-spreading effect of the heatsink, however, the TIM layer does not benefit from this. Because of its small area, the TIM layer ends up being a significant contributor to the overall Rth,J-A, and therefore the use of high thermal conductivity materials is very beneficial. The TIM layer also has a very important second role: to electrically isolate the GaN devices from the heatsink since the top of EPC GaN FETs are connected to source potential.
EPC has gathered some information on TIM materials to help designer in their search:
TIM Pads
TIM compound and greases